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\documentclass[journal=jpccck,manuscript=article]{achemso}\usepackage[T1]{fontenc}\usepackage{caption}\usepackage{booktabs}\DeclareCaptionLabelFormat{myformat}{#1~S#2}\captionsetup{labelformat=myformat}\title{Sample Title}\begin{document}\begin{table}\centering\caption{Sample caption}\begin{tabular}{cccccccc}\hline\textbf{Category} & \textbf{Category} & \textbf{Category } & \textbf{Category} & \textbf{Category} & \textbf{ Category } & \textbf{ Category } & \textbf{Category} \\\hline& & & & & & &\end{tabular}\label{tab:all-data}\end{table}\end{document}